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Synthesis and Redox Properties of Triiron Complexes Featuring Strong Fe–Fe Interactions
Author(s) -
Zhao Qinliang,
Betley Theodore A.
Publication year - 2011
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201005198
A modular hexadentate polyamide ligand directs the assembly of triiron complexes (see structure). Crystallographic studies reveal significant metal–metal bonding interactions, which are enhanced upon oxidation.