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A Cavity‐Shaped Diphosphane Displaying “Oschelating” Behavior
Author(s) -
GramageDoria Rafael,
Armspach Dominique,
Matt Dominique,
Toupet Loïc
Publication year - 2011
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201005169
Subject(s) - computer science
A molecular balance wheel : Transition metals form β‐cyclodextrin‐derived diphosphane chelate complexes (picture: ligand structure) in which a fast oscillatory motion about the metal ion takes place (“oschelating behavior”). The observed movement occurs without dissociation of the metal–phosphorus bond.