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Structurally Engineered Deprotonation/Alumination of THF and THTP with Retention of Their Cycloanionic Structures
Author(s) -
Crosbie Elaine,
GarcíaÁlvarez Pablo,
Kennedy Alan R.,
Klett Jan,
Mulvey Robert E.,
Robertson Stuart D.
Publication year - 2010
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201005119
Subject(s) - deprotonation , process (computing) , chemistry , chemical engineering , organic chemistry , computer science , engineering , ion , operating system
Engagement ring : α‐Metalated by a lithium bisamido‐bisalkylaluminate base, the sensitive cycloanionic ring of THF or THTP remains intact by engaging with both metal centers of the base residue (see structure; X=O, S).
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