Reactivity Studies of a Masked Three‐Coordinate Vanadium(II) Complex | Zendy

Tran Ba L. | Zendy; Singhal Madhavi | Zendy; Park Hyunsoo | Zendy; Lam Oanh P. | Zendy; Pink Maren | Zendy; Krzystek J. | Zendy; Ozarowski Andrew | Zendy; Telser Joshua | Zendy; Meyer Karsten | Zendy; Mindiola Daniel J. | Zendy

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Reactivity Studies of a Masked Three‐Coordinate Vanadium(II) Complex

Author(s) -

Tran Ba L.,

Singhal Madhavi,

Park Hyunsoo,

Lam Oanh P.,

Pink Maren,

Krzystek J.,

Ozarowski Andrew,

Telser Joshua,

Meyer Karsten,

Mindiola Daniel J.

Publication year - 2010

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201005029

Subject(s) - reactivity (psychology) , vanadium , ligand (biochemistry) , chemistry , center (category theory) , computer science , combinatorial chemistry , stereochemistry , crystallography , inorganic chemistry , medicine , biochemistry , alternative medicine , receptor , pathology

An arene interaction can mask a low‐valent and low‐coordinate V II complex, [(nacnac)V(Ntol 2 )] (see structure), which allows for facile coordination of terminal ligands on the vanadium center. Small‐molecule activation by this S =3/2 complex provides facile access to a wide range of ligand frameworks such as terminal V IV imido, V IV cyclopropene, V V nitride, and the first V V cyclo ‐P 3 complex (see scheme).

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