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Reactivity Studies of a Masked Three‐Coordinate Vanadium(II) Complex
Author(s) -
Tran Ba L.,
Singhal Madhavi,
Park Hyunsoo,
Lam Oanh P.,
Pink Maren,
Krzystek J.,
Ozarowski Andrew,
Telser Joshua,
Meyer Karsten,
Mindiola Daniel J.
Publication year - 2010
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201005029
Subject(s) - reactivity (psychology) , vanadium , ligand (biochemistry) , chemistry , center (category theory) , computer science , combinatorial chemistry , stereochemistry , crystallography , inorganic chemistry , medicine , biochemistry , alternative medicine , receptor , pathology
An arene interaction can mask a low‐valent and low‐coordinate V II complex, [(nacnac)V(Ntol 2 )] (see structure), which allows for facile coordination of terminal ligands on the vanadium center. Small‐molecule activation by this S =3/2 complex provides facile access to a wide range of ligand frameworks such as terminal V IV imido, V IV cyclopropene, V V nitride, and the first V V cyclo ‐P 3 complex (see scheme).