Rhodium(II)‐Catalyzed Cross‐Coupling of Diazo Compounds | Zendy

Hansen Jørn H. | Zendy; Parr Brendan T. | Zendy; Pelphrey Philip | Zendy; Jin Quihui | Zendy; Autschbach Jochen | Zendy; Davies Huw M. L. | Zendy

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Rhodium(II)‐Catalyzed Cross‐Coupling of Diazo Compounds

Author(s) -

Hansen Jørn H.,

Parr Brendan T.,

Pelphrey Philip,

Jin Quihui,

Autschbach Jochen,

Davies Huw M. L.

Publication year - 2011

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201004923

Subject(s) - diazo , rhodium , aryl , combinatorial chemistry , coupling (piping) , nothing , chemistry , computer science , alkyl , catalysis , database , organic chemistry , philosophy , materials science , epistemology , metallurgy

Nothing left to chance : A convenient protocol for selective cross‐coupling of diazo compounds for the convergent synthesis of alkenes was developed (see scheme; EDG=aryl, heteroaryl, vinyl; R=O‐alkyl, aryl). The selectivity control elements were identified by ReactIR and DFT calculations and provide a framework for the design of viable diazo coupling reactions.

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