Differential Ion Exchange in Elliptical Uranyl Diphosphonate Nanotubules | Zendy

Adelani Pius O. | Zendy; AlbrechtSchmitt Thomas E. | Zendy

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Differential Ion Exchange in Elliptical Uranyl Diphosphonate Nanotubules

Author(s) -

Adelani Pius O.,

AlbrechtSchmitt Thomas E.

Publication year - 2010

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201004797

Subject(s) - uranyl , phosphonate , crystallography , ion , materials science , ion exchange , mineralogy , chemistry , organic chemistry

Nanotubular bells : A simple route to a uranyl diphosphonate with an elliptical nanotubular structure has been developed (see picture; C black, O red, Cs blue, F yellow, UO 7 green pentagonal bipyramids, phosphonate violet tetrahedra). The interior of the nanotubules provides a different chemical environment than the exterior with regards to the exchange of Cs + cations for Ag + cations, thus demonstrating that uranyl nanotubules are functional materials.

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