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Click Syntheses of 1,2,3‐Triazolylbiferrocenyl Dendrimers and the Selective Roles of the Inner and Outer Ferrocenyl Groups in the Redox Recognition of ATP 2− and Pd 2+
Author(s) -
Djeda Rodrigue,
Rapakousiou Amalia,
Liang Liyuan,
Guidolin Nicola,
Ruiz Jaime,
Astruc Didier
Publication year - 2010
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201004756
Subject(s) - dendrimer , valence (chemistry) , redox , electrochemistry , combinatorial chemistry , click chemistry , chemistry , catalysis , computer science , nanotechnology , electrode , materials science , organic chemistry
This way and that : Triazolylbiferrocenyl dendrimers can be synthesized with up to 729 termini. Oxidation results in isolable mixed‐valence dendrimers (see picture). In electrochemical studies, these species can recognize ATP 2− and Pd II , and they can be used to stabilize Pd nanoparticle catalysts.