Click Syntheses of 1,2,3‐Triazolylbiferrocenyl Dendrimers and the Selective Roles of the Inner and Outer Ferrocenyl Groups in the Redox Recognition of ATP 2−  and Pd 2+ | Zendy

Djeda Rodrigue | Zendy; Rapakousiou Amalia | Zendy; Liang Liyuan | Zendy; Guidolin Nicola | Zendy; Ruiz Jaime | Zendy; Astruc Didier | Zendy

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Click Syntheses of 1,2,3‐Triazolylbiferrocenyl Dendrimers and the Selective Roles of the Inner and Outer Ferrocenyl Groups in the Redox Recognition of ATP 2− and Pd 2+

Author(s) -

Djeda Rodrigue,

Rapakousiou Amalia,

Liang Liyuan,

Guidolin Nicola,

Ruiz Jaime,

Astruc Didier

Publication year - 2010

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201004756

Subject(s) - dendrimer , valence (chemistry) , redox , electrochemistry , combinatorial chemistry , click chemistry , chemistry , catalysis , computer science , nanotechnology , electrode , materials science , organic chemistry

This way and that : Triazolylbiferrocenyl dendrimers can be synthesized with up to 729 termini. Oxidation results in isolable mixed‐valence dendrimers (see picture). In electrochemical studies, these species can recognize ATP 2− and Pd II , and they can be used to stabilize Pd nanoparticle catalysts.

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