Oxidation of  closo ‐[B 12 Cl 12 ] 2−  to the Radical Anion [B 12 Cl 12 ] .−  and to Neutral B 12 Cl 12 | Zendy

Boeré René T. | Zendy; Kacprzak Sylwia | Zendy; Keßler Mathias | Zendy; Knapp Carsten | Zendy; Riebau Rainer | Zendy; Riedel Sebastian | Zendy; Roemmele Tracey L. | Zendy; Rühle Monika | Zendy; Scherer Harald | Zendy; Weber Stefan | Zendy

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Oxidation of closo ‐[B 12 Cl 12 ] 2− to the Radical Anion [B 12 Cl 12 ] .− and to Neutral B 12 Cl 12

Author(s) -

Boeré René T.,

Kacprzak Sylwia,

Keßler Mathias,

Knapp Carsten,

Riebau Rainer,

Riedel Sebastian,

Roemmele Tracey L.,

Rühle Monika,

Scherer Harald,

Weber Stefan

Publication year - 2011

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201004755

Subject(s) - chemistry , ion , sulfur , crystallography , inorganic chemistry , analytical chemistry (journal) , organic chemistry

Strong as an ox : Oxidation of the perchlorinated dodecaborate [B 12 Cl 12 ] 2− by AsF 5 in liquid sulfur dioxide leads to the Jahn–Teller‐distorted radical anion [B 12 Cl 12 ] .− and to neutral B 12 Cl 12 (see structure; B brown, Cl green). The formation of both compounds has been verified by a combination of several theoretical and experimental methods (pictured: cyclic voltammogram of [B 12 Cl 12 ] 2− in liquid SO 2 ).

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