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Triplet–Triplet Energy Transfer in DNA: A Process that Occurs on the Nanosecond Timescale
Author(s) -
Curutchet Carles,
Voityuk Alexander A.
Publication year - 2011
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201004732
Subject(s) - nucleobase , excited state , energy transfer , dna , nanosecond , energy (signal processing) , physics , process (computing) , triplet state , computer science , chemical physics , statistical physics , chemistry , atomic physics , quantum mechanics , laser , biochemistry , operating system
No will to wander : Triplet–triplet electronic energy transfer in polyA–polyT DNA sequences was studied by using semiempirical quantum‐chemical methods coupled to classical molecular‐dynamics simulations. Triplet excited states in DNA were found to be almost completely localized on single nucleobases; the characteristic time for their migration along the A–A and T–T stacks (see picture) was found to be 0.8 and 6.4 ns.
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