Ionic‐Liquid‐Tethered Nanoparticles: Hybrid Electrolytes | Zendy

Moganty Surya S. | Zendy; Jayaprakash N. | Zendy; Nugent Jennifer L. | Zendy; Shen J. | Zendy; Archer Lynden A. | Zendy

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Ionic‐Liquid‐Tethered Nanoparticles: Hybrid Electrolytes

Author(s) -

Moganty Surya S.,

Jayaprakash N.,

Nugent Jennifer L.,

Shen J.,

Archer Lynden A.

Publication year - 2010

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201004551

Subject(s) - ionic conductivity , electrolyte , materials science , anode , lithium (medication) , ionic bonding , ionic liquid , thermal stability , chemical engineering , nanotechnology , chemistry , ion , organic chemistry , electrode , engineering , catalysis , medicine , endocrinology

A new class of solventless electrolytes was created by tethering ionic liquids to hard inorganic ZrO 2 nanostructures (see picture; NIM=nanoscale ionic material). These hybrid fluids exhibit exceptional redox stability windows, excellent thermal stability, good lithium transference numbers, long‐term interfacial stability in the presence of a lithium anode and, when doped with lithium salt, reasonable ionic conductivities.

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