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Solid‐State Conversion of the Solvated Dimer [{ t BuZn(μ‐O t Bu)(thf)} 2 ] into a Long Overlooked Trimeric [{ t BuZnO t Bu} 3 ] Species
Author(s) -
Lewiński Janusz,
Dutkiewicz Michał,
Lesiuk Michał,
Śliwiński Witold,
Zelga Karolina,
Justyniak Iwona,
Lipkowski Janusz
Publication year - 2010
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201004504
Subject(s) - trimer , alkoxide , dimer , cubane , solid state , crystallography , content (measure theory) , chemistry , crystal structure , mathematics , organic chemistry , mathematical analysis , catalysis
Zinc links : Solid‐state desolvation of the dimeric alkoxide [{ t BuZn(μ‐O t Bu)(thf)} 2 ] leads to a trimer [{ t BuZnO t Bu} 3 ] with a unique core structure; subsequent grinding affords the tetrameric cubane [{ t BuZnO t Bu} 4 ]. This approach demonstrates a new direction in the generation of metal alkoxide clusters.