Solid‐State Conversion of the Solvated Dimer [{ t BuZn(μ‐O t Bu)(thf)} 2 ] into a Long Overlooked Trimeric [{ t BuZnO t Bu} 3 ] Species | Zendy

Lewiński Janusz | Zendy; Dutkiewicz Michał | Zendy; Lesiuk Michał | Zendy; Śliwiński Witold | Zendy; Zelga Karolina | Zendy; Justyniak Iwona | Zendy; Lipkowski Janusz | Zendy

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Solid‐State Conversion of the Solvated Dimer [{ t BuZn(μ‐O t Bu)(thf)} 2 ] into a Long Overlooked Trimeric [{ t BuZnO t Bu} 3 ] Species

Author(s) -

Lewiński Janusz,

Dutkiewicz Michał,

Lesiuk Michał,

Śliwiński Witold,

Zelga Karolina,

Justyniak Iwona,

Lipkowski Janusz

Publication year - 2010

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201004504

Subject(s) - trimer , alkoxide , dimer , cubane , solid state , crystallography , content (measure theory) , chemistry , crystal structure , mathematics , organic chemistry , mathematical analysis , catalysis

Zinc links : Solid‐state desolvation of the dimeric alkoxide [{ t BuZn(μ‐O t Bu)(thf)} 2 ] leads to a trimer [{ t BuZnO t Bu} 3 ] with a unique core structure; subsequent grinding affords the tetrameric cubane [{ t BuZnO t Bu} 4 ]. This approach demonstrates a new direction in the generation of metal alkoxide clusters.

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