Mechanical Bond Formation by Radical Templation | Zendy

Li Hao | Zendy; Fahrenbach Albert C. | Zendy; Dey Sanjeev K. | Zendy; Basu Subhadeep | Zendy; Trabolsi Ali | Zendy; Zhu Zhixue | Zendy; Botros Youssry Y. | Zendy; Stoddart J. Fraser | Zendy

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Mechanical Bond Formation by Radical Templation

Author(s) -

Li Hao,

Fahrenbach Albert C.,

Dey Sanjeev K.,

Basu Subhadeep,

Trabolsi Ali,

Zhu Zhixue,

Botros Youssry Y.,

Stoddart J. Fraser

Publication year - 2010

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201004488

Subject(s) - chemistry , triethanolamine , rotaxane , viologen , electron transfer , ruthenium , photochemistry , radical ion , bipyridine , quinoxaline , derivative (finance) , polymer chemistry , crystallography , organic chemistry , crystal structure , catalysis , ion , analytical chemistry (journal) , supramolecular chemistry , financial economics , economics

A radical interaction has been employed as the recognition motif in the template‐directed synthesis of a [2]rotaxane composed of cyclobis(paraquat‐ p ‐phenylene) and a viologen derivative. The ruthenium tris(bipyridine)/triethanolamine system is used as the electron‐transfer photocatalyst to generate the necessary radical cation components that result in the formation of an inclusion complex. A stoppering reaction follows to form the mechanical bond.

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