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Highly Enantioselective Hydroxycarbonylation and Alkoxycarbonylation of Alkenes using Dipalladium Complexes as Precatalysts
Author(s) -
Konrad Tina M.,
Fuentes José A.,
Slawin Alexandra M. Z.,
Clarke Matthew L.
Publication year - 2010
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201004415
Subject(s) - enantioselective synthesis , phosphine , catalysis , palladium , chemistry , organic chemistry , combinatorial chemistry , computer science
Joined at Pd : Novel palladium catalysts like 1 , in which the planar‐chiral phosphine acts as a bridging ligand, have been developed. These dimetallic complexes are highly enantioselective catalysts in the hydroxycarbonylation of alkenes, a reaction that has proven problematic over the years. PTSA= para ‐toluenesulfonic acid.