Premium
Halide‐Directed Assembly of Multicomponent Systems: Highly Ordered Au I –Ag I Molecular Aggregates
Author(s) -
Koshevoy Igor O.,
Karttunen Antti J.,
Shakirova Julia R.,
Melnikov Alexei S.,
Haukka Matti,
Tunik Sergey P.,
Pakkanen Tapani A.
Publication year - 2010
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201004386
Subject(s) - halide , cationic polymerization , bimetallic strip , cluster (spacecraft) , crystallography , metal , chemistry , physics , inorganic chemistry , computer science , polymer chemistry , organic chemistry , programming language
Triangular cationic belts [Au 3 {PPh 2 (C 6 H 4 ) n PPh 2 } 3 ] 3+ enclose bimetallic clusters [Au w Ag x (C 2 Ph) y X z ] in molecular aggregates obtained by halide (X)‐directed assembly of multicomponent systems. The largest aggregate consists of a central metal alkynyl halide cluster [Au 18 Ag 30 (C 2 Ph) 36 Cl 9 ] 3+ inside a [Au 3 {PPh 2 (C 6 H 4 ) 5 PPh 2 } 3 ] 3+ belt and comprises 51 metal atoms (see picture; Ag green, Au yellow, Cl violet, P red).
Accelerating Research
Robert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom
Address
John Eccles HouseRobert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom