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Linear‐Selective Rhodium(I)‐Catalyzed Addition of Arylboronic Acids to Allyl Sulfones
Author(s) -
Tsui Gavin C.,
Lautens Mark
Publication year - 2010
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201004345
Subject(s) - rhodium , scope (computer science) , catalysis , chemistry , combinatorial chemistry , organic chemistry , computer science , programming language
One step further : The rhodium(I)‐catalyzed addition of readily available arylboronic acids to allyl sulfones affords the linear (formal) hydroarylated products in good yields and excellent regioselectivities. The reaction broadens the scope of unactivated alkenes that can participate in rhodium‐catalyzed addition reactions.