Enantioselective Construction of Bridged Multicyclic Skeletons: Intermolecular [2+2+2] Cycloaddition/Intramolecular Diels–Alder Reaction Cascade | Zendy

Kobayashi Masayuki | Zendy; Suda Takeshi | Zendy; Noguchi Keiichi | Zendy; Tanaka Ken | Zendy

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Enantioselective Construction of Bridged Multicyclic Skeletons: Intermolecular [2+2+2] Cycloaddition/Intramolecular Diels–Alder Reaction Cascade

Author(s) -

Kobayashi Masayuki,

Suda Takeshi,

Noguchi Keiichi,

Tanaka Ken

Publication year - 2011

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201004150

Subject(s) - intramolecular force , enantioselective synthesis , cationic polymerization , cycloaddition , intermolecular force , rhodium , chemistry , diels–alder reaction , amide , cascade , stereochemistry , combinatorial chemistry , organic chemistry , catalysis , molecule , chromatography

Bridging a gap : A cationic rhodium(I)/ligand complex catalyzes the title reaction of alkynes and amide‐linked 1,5‐dienes, leading to bridged multicyclic compounds, with high chemo‐, regio‐, and enantioselectivity (see scheme; Bn=benzyl).

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