Heterolytic SS Bond Cleavage by a Purely Carbogenic Frustrated Lewis Pair | Zendy

Inés Blanca | Zendy; Holle Sigrid | Zendy; Goddard Richard | Zendy; Alcarazo Manuel | Zendy

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Heterolytic SS Bond Cleavage by a Purely Carbogenic Frustrated Lewis Pair

Author(s) -

Inés Blanca,

Holle Sigrid,

Goddard Richard,

Alcarazo Manuel

Publication year - 2010

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201004149

Subject(s) - heterolysis , frustrated lewis pair , allene , boranes , carbene , chemistry , lewis acids and bases , cleavage (geology) , bond cleavage , medicinal chemistry , stereochemistry , photochemistry , organic chemistry , catalysis , materials science , composite material , fracture (geology) , boron

Boranes were getting borin' : Owing to the Lewis acidic character of the central carbon atom, a bisfluorenyl‐substituted allene 1 could be used instead of B(C 6 F 5 ) 3 for the generation of frustrated Lewis pairs. Mixtures of the allene and the bulky N‐heterocyclic carbene shown in red (Dipp=diisopropylphenyl) caused heterolytic cleavage of the SS bond in disulfides.

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