[Cp 2 Ti III (NCy) 2 CTi III Cp 2 ]: A Transient Titanocene Carbene Complex? | Zendy

Theilmann Oliver | Zendy; Ruhmann Martin | Zendy; Villinger Alexander | Zendy; Schulz Axel | Zendy; Seidel Wolfram W. | Zendy; Kaleta Katharina | Zendy; Beweries Torsten | Zendy; Arndt Perdita | Zendy; Rosenthal Uwe | Zendy

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[Cp 2 Ti III (NCy) 2 CTi III Cp 2 ]: A Transient Titanocene Carbene Complex?

Author(s) -

Theilmann Oliver,

Ruhmann Martin,

Villinger Alexander,

Schulz Axel,

Seidel Wolfram W.,

Kaleta Katharina,

Beweries Torsten,

Arndt Perdita,

Rosenthal Uwe

Publication year - 2010

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201004145

Subject(s) - carbene , yield (engineering) , quenching (fluorescence) , physics , chemistry , catalysis , organic chemistry , thermodynamics , fluorescence , quantum mechanics

Carbene or not carbene? By utilizing [Cp 2 Ti(η 2 ‐Me 3 SiC 2 SiMe 3 )] (Cp=C 5 H 5 ) as both a reducing and a quenching agent in the reaction with RNCNR, the first paramagnetic dinuclear titanocene(III) carbene‐like complex is prepared in good yield. The complex features the topology of a four‐membered N‐heterocyclic carbene species but with a Ti III center as part of the heterocycle.

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