Smart Self‐Assemblies Based on a Surfactant‐Encapsulated Photoresponsive Polyoxometalate Complex | Zendy

Yan Yi | Zendy; Wang Huanbing | Zendy; Li Bao | Zendy; Hou Guangfeng | Zendy; Yin Zhendong | Zendy; Wu Lixin | Zendy; Yam Vivian W. W. | Zendy

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Smart Self‐Assemblies Based on a Surfactant‐Encapsulated Photoresponsive Polyoxometalate Complex

Author(s) -

Yan Yi,

Wang Huanbing,

Li Bao,

Hou Guangfeng,

Yin Zhendong,

Wu Lixin,

Yam Vivian W. W.

Publication year - 2010

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201004143

Subject(s) - polyoxometalate , pulmonary surfactant , materials science , chemical engineering , nanotechnology , chemistry , organic chemistry , catalysis , engineering

Smart POMs : A surfactant‐encapsulated organic‐grafted polyoxometalate (POM) is synthesized by grafting a photoresponsive azobenzene group to an Anderson‐type POM cluster. Self‐assemblies of the hybrid complexes exhibit photocontrolled reversible aggregation and morphological change as a result of photoisomerization‐induced structural alternation (see figure).

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