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Controlling the Transformation of Primary into Quaternary Structures: Towards Hierarchically Built‐Up Twisted Fibers
Author(s) -
López Juan Luis,
Atienza Carmen,
Seitz Wolfgang,
Guldi Dirk M.,
Martín Nazario
Publication year - 2010
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201004127
Subject(s) - lamellar structure , quaternary , materials science , tetrathiafulvalene , nanofiber , nanotechnology , composite material , geology , molecule , chemistry , paleontology , organic chemistry
From the ground up : In the hierarchical organization of cyanurate 1 and π‐extended tetrathiafulvalene (π‐exTTF) 2 —an example of the controlled one‐, two, and three‐dimensional assembly of nonplanar building blocks on different scales—highly ordered lamellar crystalline packing based on π–π interactions between π‐exTTF units ensured the unidirectional growth of twisted nanofibers as the quaternary structure.