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Exploiting Non‐Innocent Ligands to Prepare Masked Palladium(0) Complexes
Author(s) -
Smith Dan A.,
Batsanov Andrei S.,
Costuas Karine,
Edge Ruth,
Apperley David C.,
Collison David,
Halet JeanFrançois,
Howard Judith A. K.,
Dyer Philip W.
Publication year - 2010
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201003946
Subject(s) - bimetallic strip , palladium , chlorobenzene , ligand (biochemistry) , chemistry , photochemistry , combinatorial chemistry , catalysis , organic chemistry , receptor , biochemistry
Is it or isn't it : Reaction of [PdMe 2 (tmeda)] with pyridyl‐ N ‐ di ( tert ‐butyl)phosphinoimine spontaneously affords an unusual bimetallic palladium(I) ligand‐based biradical complex, which behaves as a “masked” form of Pd 0 in its reactions with neutral ligands and chlorobenzene.