Exploiting Non‐Innocent Ligands to Prepare Masked Palladium(0) Complexes | Zendy

Smith Dan A. | Zendy; Batsanov Andrei S. | Zendy; Costuas Karine | Zendy; Edge Ruth | Zendy; Apperley David C. | Zendy; Collison David | Zendy; Halet JeanFrançois | Zendy; Howard Judith A. K. | Zendy; Dyer Philip W. | Zendy

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Exploiting Non‐Innocent Ligands to Prepare Masked Palladium(0) Complexes

Author(s) -

Smith Dan A.,

Batsanov Andrei S.,

Costuas Karine,

Edge Ruth,

Apperley David C.,

Collison David,

Halet JeanFrançois,

Howard Judith A. K.,

Dyer Philip W.

Publication year - 2010

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201003946

Subject(s) - bimetallic strip , palladium , chlorobenzene , ligand (biochemistry) , chemistry , photochemistry , combinatorial chemistry , catalysis , organic chemistry , receptor , biochemistry

Is it or isn't it : Reaction of [PdMe 2 (tmeda)] with pyridyl‐ N ‐ di ( tert ‐butyl)phosphinoimine spontaneously affords an unusual bimetallic palladium(I) ligand‐based biradical complex, which behaves as a “masked” form of Pd 0 in its reactions with neutral ligands and chlorobenzene.

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