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Subazaphenalenephthalocyanine: A Subphthalocyanine Analogue Bearing a Six‐Membered Ring Unit
Author(s) -
Zhu Hua,
Shimizu Soji,
Kobayashi Nagao
Publication year - 2010
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201003929
Subject(s) - unit (ring theory) , ring (chemistry) , core (optical fiber) , plot (graphics) , electrochemistry , molecule , bearing (navigation) , computer science , chemistry , crystallography , mathematics , telecommunications , organic chemistry , artificial intelligence , statistics , mathematics education , electrode
At the core : A novel core‐modified subphthalocyanine analogue has been synthesized (see structure; Cl green, red O, blue N). This molecule comprises a six‐membered ring unit in place of a five‐membered ring unit and exhibits unique spectroscopic (see plot) and electrochemical properties originating from the azaphenalene‐containing 14π‐electron conjugation system.