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Palladium‐Catalyzed Carbonylative CH Activation of Heteroarenes
Author(s) -
Wu XiaoFeng,
Anbarasan Pazhamalai,
Neumann Helfried,
Beller Matthias
Publication year - 2010
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201003895
Subject(s) - carbonylation , catalysis , palladium , chemistry , coupling reaction , dimethylformamide , medicinal chemistry , organic chemistry , combinatorial chemistry , carbon monoxide , solvent
Not only carbonylation : The first carbonylative cross‐coupling reactions towards ketones using CH activation have been developed. Various heteroarenes, such as oxazoles, thiazoles, and imidazoles were used as coupling partners in this methodology. DBU=1,8‐diazabicyclo[5.4.0]undec‐7‐ene, dppp=1,3‐bisdiphenylphosphinopropane, DMF= N , N ‐dimethylformamide.
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