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Scalable Synthesis of Tavorite LiFeSO 4 F and NaFeSO 4 F Cathode Materials
Author(s) -
Tripathi Rajesh,
Ramesh T. N.,
Ellis Brian L.,
Nazar Linda F.
Publication year - 2010
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201003743
Subject(s) - scalability , cathode , computer science , information retrieval , chemistry , database
Single‐phase tavorite , LiFeSO 4 F, is crystallized in tetraethylene glycol at 220 °C to give an electrochemically highly active material. This route obviates the need for expensive ionic liquids and can be extended to the synthesis of NaFeSO 4 F, whose structure solution, along with that of the parent framework FeSO 4 F, provides understanding of ion mobility.