Copper‐Catalyzed Rearrangement of Tertiary Amines through Oxidation of Aliphatic CH Bonds in Air or Oxygen: Direct Synthesis of α‐Amino Acetals | Zendy

Tian JieSheng | Zendy; Loh TeckPeng | Zendy

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Copper‐Catalyzed Rearrangement of Tertiary Amines through Oxidation of Aliphatic CH Bonds in Air or Oxygen: Direct Synthesis of α‐Amino Acetals

Author(s) -

Tian JieSheng,

Loh TeckPeng

Publication year - 2010

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201003646

Subject(s) - tetramethylethylenediamine , chemistry , catalysis , copper , oxygen , photochemistry , mechanism (biology) , reaction mechanism , isotopic labeling , oxygen atom , medicinal chemistry , polymer chemistry , organic chemistry , molecule , philosophy , epistemology

A surprising turn of events : Mechanistic studies, including trapping, control, and isotope‐labeling experiments, led to the proposal of a rearrangement mechanism involving oxidation of aliphatic CH bonds (see scheme; TMEDA=tetramethylethylenediamine).

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