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Copper‐Promoted and Copper‐Catalyzed Intermolecular Alkene Diamination
Author(s) -
Sequeira Fatima C.,
Turnpenny Benjamin W.,
Chemler Sherry R.
Publication year - 2010
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201003499
Subject(s) - intramolecular force , chemistry , alkene , amination , olefin fiber , hydroamination , enantioselective synthesis , combinatorial chemistry , catalysis , intermolecular force , nucleophile , organic chemistry , molecule
Simply copper : Copper(II)‐promoted intra‐ and intermolecular olefin diaminations bring together two differently functionalized amines into a vicinal relationship. High diastereoselectivity was obtained with chiral alkenes and results of the asymmetric catalysis are promising.