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Electron Transfer in Peptides: The Influence of Charged Amino Acids
Author(s) -
Gao Jian,
Müller Pavel,
Wang Min,
Eckhardt Sonja,
Lauz Miriam,
Fromm Katharina M.,
Giese Bernd
Publication year - 2011
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201003389
Subject(s) - coulomb , electron transfer , peptide , transfer (computing) , electron , chemistry , ammonium , computer science , information retrieval , physics , biochemistry , quantum mechanics , organic chemistry , parallel computing
Charging off : The ammonium group in the peptide shown leads to a tenfold increase of the electron‐transfer rate compared to that in a fully protected system. This is explained by Coulomb's law and the Marcus theory.