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Anomalous Stoichiometry, Layered Structure, and Magnetic Ordering for the Prussian Blue Analogue [NEt 4 ] 2 [Mn II 3 (CN) 8 ]
Author(s) -
Her JaeHyuk,
Stephens Peter W.,
Kareis Christopher M.,
Moore Joshua G.,
Miller Joel S.
Publication year - 2010
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201003381
Subject(s) - prussian blue , stoichiometry , chemistry , materials science , crystallography , inorganic chemistry , electrochemistry , electrode
Unprecedented : Atypical of Prussian blue structured materials, Mn II and [NEt 4 ]CN react to form [NEt 4 ] 2 Mn 3 (CN) 8 possessing layers of octahedral [Mn II (CN) 6 ] 4− bonded to two high‐spin tetrahedral Mn II sites (see structure; yellow and red Mn, black C, blue N).