Cation‐Exchange Porosity Tuning in Anionic Metal–Organic Frameworks for the Selective Separation of Gases and Vapors and for Catalysis | Zendy

Quartapelle Procopio Elsa | Zendy; Linares Fátima | Zendy; Montoro Carmen | Zendy; Colombo Valentina | Zendy; Maspero Angelo | Zendy; Barea Elisa | Zendy; Navarro Jorge A. R. | Zendy

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Cation‐Exchange Porosity Tuning in Anionic Metal–Organic Frameworks for the Selective Separation of Gases and Vapors and for Catalysis

Author(s) -

Quartapelle Procopio Elsa,

Linares Fátima,

Montoro Carmen,

Colombo Valentina,

Maspero Angelo,

Barea Elisa,

Navarro Jorge A. R.

Publication year - 2010

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201003314

Subject(s) - cyclohexane , catalysis , acetylene , benzene , metal organic framework , methane , porosity , adsorption , inorganic chemistry , chemistry , metal , carbon dioxide , nitrogen , hydrocarbon , gas separation , chemical engineering , materials science , organic chemistry , biochemistry , membrane , engineering

Temperature matters! The separation efficiency of complex mixtures of gases (acetylene, carbon dioxide, methane, nitrogen) and vapors (benzene, cyclohexane) by adsorption on A[Cu 3 (μ 3 ‐OH)(μ 3 ‐4‐carboxypyrazolato) 3 ] (A@ 1 ) metal–organic frameworks depends on temperature and the extraframework cation A (see picture). NH 4 @ 1 also behaves as an oxidation catalyst.

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