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Hybrid Uranium–Oxalate Fullerene Topology Cage Clusters
Author(s) -
Ling Jie,
Wallace Christine M.,
Szymanowski Jennifer E. S.,
Burns Peter C.
Publication year - 2010
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201003197
Subject(s) - fullerene , oxalate , cage , aqueous solution , topology (electrical circuits) , cluster (spacecraft) , polyhedron , uranyl , chemistry , uranium , materials science , inorganic chemistry , organic chemistry , computer science , geometry , mathematics , combinatorics , metallurgy , programming language
Fullerene′s topology : Inorganic–organic hybrid cage clusters containing 36 and 60 uranyl peroxide polyhedra and 6 or 30 oxalate groups (see representation of a {U 60 } cluster) self‐assemble in aqueous solution under ambient conditions. These clusters, which are derivatives of fullerene topologies, were crystallized for structure analysis, and are readily dissolved intact in water.