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Facile Access to Key Reactive Intermediates in the Pd/PR 3 ‐Catalyzed Telomerization of 1,3‐Butadiene
Author(s) -
Hausoul Peter J. C.,
Parvulescu Andrei N.,
Lutz Martin,
Spek Anthony L.,
Bruijnincx Pieter C. A.,
Weckhuysen Bert M.,
Klein Gebbink Robertus J. M.
Publication year - 2010
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201003090
Subject(s) - telomerization , 1,3 butadiene , catalysis , key (lock) , chemistry , reactive intermediate , combinatorial chemistry , photochemistry , computer science , organic chemistry , computer security
Found at last : A simple and efficient one‐pot synthesis procedure leads to several cationic [Pd(1,2,3,7,8‐η 5 ‐octa‐2,7‐dien‐1‐yl)(PR 3 )] + complexes (see structure; Pd pink, O red, P orange), which are the long sought‐after key reactive intermediates in the Pd/PR 3 ‐catalyzed telomerization of butadiene.