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Metal‐Mediated Oxidative Cross‐Coupling of Terminal Alkynes: A Promising Strategy for Alkyne Synthesis
Author(s) -
Shao Zhihui,
Peng Fangzhi
Publication year - 2010
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201003081
Subject(s) - alkyne , terminal (telecommunication) , oxidative phosphorylation , combinatorial chemistry , heteroatom , chemistry , coupling (piping) , organic chemistry , materials science , computer science , catalysis , biochemistry , ring (chemistry) , telecommunications , metallurgy
Oxidative heterocoupling of terminal alkynes mediated by metal complexes has emerged as a promising new strategy for the incorporation of alkynyl functionality into organic molecules (see scheme). Recent key developments in the construction of C sp C sp 3, C sp C sp 2, C sp C sp , and C sp heteroatom bonds are highlighted.