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The Reaction of White Phosphorus with NO + /NO 2 + [Al(OR F ) 4 ] − : The [P 4 NO] + Cluster Formed by an Unexpected Nitrosonium Insertion
Author(s) -
Köchner Tobias,
Riedel Sebastian,
Lehner Anna J.,
Scherer Harald,
Raabe Ines,
Engesser Tobias A.,
Scholz Franziska W.,
Gellrich Urs,
Eiden Philipp,
Paz Schmidt Roberto A.,
Plattner Dietmar A.,
Krossing Ingo
Publication year - 2010
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201003031
Subject(s) - content (measure theory) , phosphorus , white phosphorus , chemistry , physics , organic chemistry , mathematics , mathematical analysis
An appealing couple : The unprecedented insertion of the nitrosonium cation into a tetrahedral edge of white phosphorus forms the highly reactive [P 4 NO] + cation (see picture). The synthesis, characterization, and applications are discussed, and NO 2 [Al(OC(CF 3 ) 3 ) 4 ] is presented as an easily synthesized oxidant.