Catalytic Hydrogenation of Norbornadiene by a Rhodium Complex in a Self‐Folding Cavitand | Zendy

Sarmentero Maria Angeles | Zendy; FernándezPérez Héctor | Zendy; Zuidema Erik | Zendy; Bo Carles | Zendy; VidalFerran Anton | Zendy; Ballester Pablo | Zendy

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Catalytic Hydrogenation of Norbornadiene by a Rhodium Complex in a Self‐Folding Cavitand

Author(s) -

Sarmentero Maria Angeles,

FernándezPérez Héctor,

Zuidema Erik,

Bo Carles,

VidalFerran Anton,

Ballester Pablo

Publication year - 2010

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201003026

Subject(s) - cavitand , norbornadiene , chemistry , norbornene , rhodium , selectivity , ligand (biochemistry) , photochemistry , catalysis , organic chemistry , polymerization , molecule , supramolecular chemistry , biochemistry , polymer , receptor

It's a wrap! The inclusion of [Rh(nbd) 2 ]BF 4 (nbd=norbornadiene) in a deep‐cavity cavitand produces a catalytically active species that promotes the hydrogenation of norbornadiene to norbornene (see picture). The structure of the cavitand acts as a second‐sphere ligand and modifies the stability, selectivity, and reactivity observed for the free organometallic complex in solution.

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