Spontaneous Dihydrogen Activation by Neutral TaO 4  Complex at Cryogenic Temperatures | Zendy

Zhou Mingfei | Zendy; Wang Caixia | Zendy; Li Zhen hua | Zendy; Zhuang Jia | Zendy; Zhao Yanying | Zendy; Zheng Xuming | Zendy; Fan Kangnian | Zendy

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Spontaneous Dihydrogen Activation by Neutral TaO 4 Complex at Cryogenic Temperatures

Author(s) -

Zhou Mingfei,

Wang Caixia,

Li Zhen hua,

Zhuang Jia,

Zhao Yanying,

Zheng Xuming,

Fan Kangnian

Publication year - 2010

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201003001

Subject(s) - cleave , hydrogen , catalysis , argon , chemistry , thermodynamics , materials science , computer science , physics , organic chemistry , enzyme

Get active : Neutral TaO 4 d 0 complex is able to cleave dihydrogen heterolytically and spontaneously to form [HTaO(OH)(η 2 ‐O 2 )] in solid argon at cryogenic temperatures. Theoretical calculations predict that the hydrogen atoms in [HTaO(OH)(η 2 ‐O 2 )] can easily be transferred to organic compounds. Thus, TaO 4 can serve as a model catalyst for hydrogenation reactions.

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