Synthesis, Isolation, and Characterization of 1,1‐DiGrignard and 1,1‐Dizincio Silanes | Zendy

Dobrovetsky Roman | Zendy; BravoZhivotovskii Dmitry | Zendy; Tumanskii Boris | Zendy; Botoshansky Mark | Zendy; Apeloig Yitzhak | Zendy

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Synthesis, Isolation, and Characterization of 1,1‐DiGrignard and 1,1‐Dizincio Silanes

Author(s) -

Dobrovetsky Roman,

BravoZhivotovskii Dmitry,

Tumanskii Boris,

Botoshansky Mark,

Apeloig Yitzhak

Publication year - 2010

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201002876

Subject(s) - transmetalation , silane , silanes , characterization (materials science) , tetrahydrofuran , vicinal , silylation , chemistry , lithium (medication) , combinatorial chemistry , organic chemistry , nanotechnology , materials science , catalysis , psychology , solvent , psychiatry

Two metals are better than one : A cyclic 1,1‐dimagnesiosilane, a 1,1‐di(chloromagnesio)silane, and a 1,1‐di(chlorozincio)silane have been synthesized using transmetalation reactions (see scheme; THF=tetrahydrofuran) and characterized by X‐ray crystallography. Cyclic 1,1‐dimagnesiosilane was studied in redox reactions that led to a lithium‐substituted silyl radical and a vicinal 1,2‐dilithiosilane.

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