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An Isolable Mixed P,S‐Bis(ylide) as an Asymmetric Carbon Atom Source
Author(s) -
Dellus Nicolas,
Kato Tsuyoshi,
Bagán Xavier,
SaffonMerceron Nathalie,
Branchadell Vicenç,
Baceiredo Antoine
Publication year - 2010
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201002833
Subject(s) - ylide , carbon atom , carbon fibers , atom (system on chip) , chemistry , computer science , stereochemistry , organic chemistry , algorithm , alkyl , composite number , embedded system
Heart of carbon : The first stable asymmetric bis(ylide), N , N ′‐( i Pr 2 NCH 2 CH 2 N i Pr)(Ph)PCSPh 2 , has been isolated (see picture; C black, N gray). The presence of the two different ligands causes this carbon(0) complex to behave as an asymmetric atomic carbon source.