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Subcomponent Assembly and Transmetalation of Dinuclear Helicates
Author(s) -
Dömer Johannes,
Slootweg J. Chris,
Hupka Florian,
Lammertsma Koop,
Hahn F. Ekkehardt
Publication year - 2010
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201002776
Subject(s) - transmetalation , scheme (mathematics) , palladium , bearing (navigation) , chemistry , stereochemistry , computer science , mathematics , organic chemistry , catalysis , artificial intelligence , mathematical analysis
Only available as helicates : Dinuclear zinc and nickel complexes bearing previously inaccessible N,S‐N,S ligands have been obtained in subcomponent self‐assembly reactions from complexes bearing two 2‐thiolatobenzaldehyde ligands and 4,4′‐diaminodiphenylmethane. Both complexes react with Pd(OAc) 2 by transmetalation to give the dinuclear palladium complex (see scheme).