Cover Picture: A Docosanuclear {Mo 8 Mn 14 } Cluster Based on [Mo(CN) 7 ] 4−  (Angew. Chem. Int. Ed. 30/2010) | Zendy

Wang XinYi | Zendy; Prosvirin Andrey V. | Zendy; Dunbar Kim R. | Zendy

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Cover Picture: A Docosanuclear {Mo 8 Mn 14 } Cluster Based on [Mo(CN) 7 ] 4− (Angew. Chem. Int. Ed. 30/2010)

Author(s) -

Wang XinYi,

Prosvirin Andrey V.,

Dunbar Kim R.

Publication year - 2010

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Reports

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201002741

Subject(s) - cover (algebra) , cluster (spacecraft) , cyanide , paramagnetism , crystallography , molecule , ground state , block (permutation group theory) , int , chemistry , spin (aerodynamics) , materials science , physics , condensed matter physics , combinatorics , atomic physics , inorganic chemistry , computer science , mathematics , organic chemistry , engineering , mechanical engineering , thermodynamics , programming language , operating system

A record‐breaking high‐spin state is observed in a molecule based on the [Mo(CN) 7 ] 4− building block. As K. R. Dunbar and co‐workers describe in their Communication on page 5081 ff., the anionic nanosized docosanuclear {Mo 8 Mn 14 } cluster is the first discrete compound based on [Mo(CN) 7 ] 4− . The compound contains the most paramagnetic centers (22) and the largest ground‐state spin value ( S =31) for a cyanide‐bridged cluster.

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