A Low‐Spin Ruthenium(IV)–Oxo Complex: Does the Spin State Have an Impact on the Reactivity? | Zendy

Kojima Takahiko | Zendy; Hirai Yuichirou | Zendy; Ishizuka Tomoya | Zendy; Shiota Yoshihito | Zendy; Yoshizawa Kazunari | Zendy; Ikemura Kenichiro | Zendy; Ogura Takashi | Zendy; Fukuzumi Shunichi | Zendy

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A Low‐Spin Ruthenium(IV)–Oxo Complex: Does the Spin State Have an Impact on the Reactivity?

Author(s) -

Kojima Takahiko,

Hirai Yuichirou,

Ishizuka Tomoya,

Shiota Yoshihito,

Yoshizawa Kazunari,

Ikemura Kenichiro,

Ogura Takashi,

Fukuzumi Shunichi

Publication year - 2010

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201002733

Subject(s) - reactivity (psychology) , ruthenium , chemistry , ligand (biochemistry) , spin (aerodynamics) , carboxylate , electron transfer , spin states , oxidation state , electron paramagnetic resonance , proton , medicinal chemistry , photochemistry , combinatorial chemistry , catalysis , stereochemistry , organic chemistry , inorganic chemistry , nuclear magnetic resonance , physics , thermodynamics , quantum mechanics , medicine , biochemistry , alternative medicine , receptor , pathology

Spin doesn't matter : A ruthenium(II)–aqua complex bearing a pentadentate pyridylamine with a carboxylate group as a ligand affords a seven‐coordinate low‐spin ( S =0) ruthenium(IV)–oxo complex (see structure) by oxidation through proton‐coupled electron transfer. Comparison of the reactivity of the low‐spin and an intermediate‐spin ( S =1) Ru IV –oxo complexes revealed that the spin state does not affect the reactivity of catalytic oxidation of organic compounds.

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