Topology Selection and Tautoleptic Aggregation: Formation of an Enantiomerically Pure Supramolecular Belt over a Helix | Zendy

Orentas Edvinas | Zendy; Wallentin CarlJohan | Zendy; Bergquist KarlErik | Zendy; Lund Mikael | Zendy; Butkus Eugenijus | Zendy; Wärnmark Kenneth | Zendy

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Topology Selection and Tautoleptic Aggregation: Formation of an Enantiomerically Pure Supramolecular Belt over a Helix

Author(s) -

Orentas Edvinas,

Wallentin CarlJohan,

Bergquist KarlErik,

Lund Mikael,

Butkus Eugenijus,

Wärnmark Kenneth

Publication year - 2011

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201002665

Subject(s) - homoleptic , supramolecular chemistry , hydrogen bond , monomer , helix (gastropod) , chemistry , crystallography , supramolecular polymers , tautomer , stereochemistry , topology (electrical circuits) , crystal structure , molecule , polymer , organic chemistry , mathematics , biology , combinatorics , paleontology , snail , metal

In control : An enantiomerically pure monomer selects the formation of a supramolecular belt (see structure; blue N, red O, gray C, white H) over a helix. Induced tautomerization allows for a three‐hydrogen‐bond motif to be employed in cyclic homoleptic aggregation.

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