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Organic Functionalization of Polyoxovanadates: SbN Bonds and Charge Control
Author(s) -
Antonova Elena,
Näther Christian,
Kögerler Paul,
Bensch Wolfgang
Publication year - 2011
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201002563
Subject(s) - surface modification , charge (physics) , materials science , chemistry , physics , quantum mechanics
New docking sites : SbN bonds formed under hydrothermal conditions enable the attachment of primary and secondary organic amines (see structures, C gray, N blue) to antimonato polyoxovanadate cluster anions (polyhedral representations; O red, Sb yellow), whose charge can be compensated by protonated amines.