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A General and Special Catalyst for Suzuki–Miyaura Coupling Processes
Author(s) -
Tang Wenjun,
Capacci Andrew G.,
Wei Xudong,
Li Wenjie,
White Andre,
Patel Nitinchandra D.,
Savoie Jolaine,
Gao Joe J.,
Rodriguez Sonia,
Qu Bo,
Haddad Nizar,
Lu Bruce Z.,
Krishnamurthy Dhileepkumar,
Yee Nathan K.,
Senanayake Chris H.
Publication year - 2010
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201002404
Subject(s) - catalysis , coupling (piping) , ligand (biochemistry) , palladium , coupling reaction , chemistry , combinatorial chemistry , range (aeronautics) , computer science , palladium catalyst , organic chemistry , materials science , biochemistry , receptor , metallurgy , composite material
Biaryl monophosphorus ligands containing a 2,3‐dihydrobenzo[ d ][1,3]oxaphosphole framework are highly effective for the palladium‐catalyzed Suzuki–Miyaura cross‐coupling reactions of a wide range of substrates. Ligand 1 has demonstrated excellent performance for coupling reactions of extremely hindered arylboronic acids.