Cyclodimerization of an Oxoboryl Complex Induced by  trans  Ligand Abstraction | Zendy

Braunschweig Holger | Zendy; Radacki Krzysztof | Zendy; Schneider Achim | Zendy

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Cyclodimerization of an Oxoboryl Complex Induced by trans Ligand Abstraction

Author(s) -

Braunschweig Holger,

Radacki Krzysztof,

Schneider Achim

Publication year - 2010

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201002300

Subject(s) - ligand (biochemistry) , ionic bonding , abstraction , chemistry , bromide , bridging ligand , ionic compound , bridging (networking) , stereochemistry , computer science , ion , organic chemistry , philosophy , biochemistry , receptor , epistemology , computer network

After the scattering comes the gathering : Abstracting the bromide ligand from the novel oxoboryl complex trans ‐[(Cy 3 P) 2 BrPt(BO)] has dramatic consequences: instant cyclodimerization takes place, yielding an ionic compound. The cation has an unprecedented bridging dioxodiboretanediyl ligand (see picture).

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