Metal Complexes of Chiral Möbius Aromatic [28]Hexaphyrin(1.1.1.1.1.1): Enantiomeric Separation, Absolute Stereochemistry, and Asymmetric Synthesis | Zendy

Tanaka Takayuki | Zendy; Sugita Tsutomu | Zendy; Tokuji Sumito | Zendy; Saito Shohei | Zendy; Osuka Atsuhiro | Zendy

Premium

Metal Complexes of Chiral Möbius Aromatic [28]Hexaphyrin(1.1.1.1.1.1): Enantiomeric Separation, Absolute Stereochemistry, and Asymmetric Synthesis

Author(s) -

Tanaka Takayuki,

Sugita Tsutomu,

Tokuji Sumito,

Saito Shohei,

Osuka Atsuhiro

Publication year - 2010

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201002282

Subject(s) - metalation , chemistry , enantiomer , enantioselective synthesis , absolute configuration , stereochemistry , metal , molecule , combinatorial chemistry , organic chemistry , catalysis

Twist and sort out! Chiral separation of Pd II , Ni II , and Pt II complexes of [28]hexaphyrin(1.1.1.1.1.1) was achieved by HPLC on a chiral stationary phase (see inset for CD trace). The absolute configuration for the Pd II complex was determined by X‐ray crystallography. Asymmetric metalation of hexaphyrin, achieved with a Pd II binap salt, resulted in 23 % ee. This is the first example of asymmetric synthesis of Möbius‐twisted molecules.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research