Premium
Control of Interpenetration for Tuning Structural Flexibility Influences Sorption Properties
Author(s) -
Bureekaew Sareeya,
Sato Hiroshi,
Matsuda Ryotaro,
Kubota Yoshiki,
Hirose Raita,
Kim Jungeun,
Kato Kenichi,
Takata Masaki,
Kitagawa Susumu
Publication year - 2010
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201002259
Subject(s) - sorption , flexibility (engineering) , adsorption , materials science , jungle , porosity , chemical engineering , polymer , composite material , chemistry , organic chemistry , engineering , mathematics , ecology , statistics , biology
Transforming jungle gyms : Structural flexibility and sorption behavior can be tuned by controlling the degree of interpenetration of 3D porous coordination polymers (PCPs). The architectural connectivity of PCPs, even those that are composed of the same chemical components, has a significant impact on the structural flexibility and sorption behavior, which was confirmed by coincident XRPD/adsorption measurements.