Monomeric Organoantimony(I) and Organobismuth(I) Compounds Stabilized by an NCN Chelating Ligand: Syntheses and Structures | Zendy

Šimon Petr | Zendy; de Proft Frank | Zendy; Jambor Roman | Zendy; Růžička Aleš | Zendy; Dostál Libor | Zendy

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Monomeric Organoantimony(I) and Organobismuth(I) Compounds Stabilized by an NCN Chelating Ligand: Syntheses and Structures

Author(s) -

Šimon Petr,

de Proft Frank,

Jambor Roman,

Růžička Aleš,

Dostál Libor

Publication year - 2010

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201002209

Subject(s) - steric effects , monomer , ligand (biochemistry) , chelation , chemistry , pincer movement , crystallography , combinatorial chemistry , stereochemistry , organic chemistry , polymer , biochemistry , receptor , catalysis

One on one : A combination of steric effects and MN interactions of a rigid NCN pincer ligand allows the isolation and characterization of monomeric stibinidene and bismuthinidene compounds. The structure and bonding was confirmed by crystallographic studies (see picture; Sb or Bi yellow, N blue) and calculations.

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