Premium
Encapsulated Carboxylic Acid Dimers with Compressed Hydrogen Bonds
Author(s) -
Ajami Dariush,
Tolstoy Peter M.,
Dube Henry,
Odermatt Severin,
Koeppe Benjamin,
Guo Jing,
Limbach HansHeinrich,
Rebek, Julius
Publication year - 2011
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201002182
Subject(s) - hydrogen bond , carboxylic acid , scheme (mathematics) , hydrogen , compression (physics) , chemistry , computer science , combinatorial chemistry , materials science , polymer chemistry , organic chemistry , molecule , composite material , mathematics , mathematical analysis
Under pressure : Carboxylic acid dimers enclosed in molecular capsules experience an internal pressure of about 5–10 kbar, which leads to compression of the hydrogen bonds (see scheme).