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Binary Bismuth(III) Azides: Bi(N 3 ) 3 , [Bi(N 3 ) 4 ] − , and [Bi(N 3 ) 6 ] 3−
Author(s) -
Villinger Alexander,
Schulz Axel
Publication year - 2010
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201002179
Subject(s) - bismuth , binary number , chemistry , mathematics , organic chemistry , arithmetic
Nitrogen finally meets bismuth : The synthesis of binary bismuth(III) azides Bi III (N 3 ) 3 , [Bi III (N 3 ) 4 ] − , and [Bi III (N 3 ) 6 ] 3− along with their characterization is presented for the first time and closes a chapter in main group chemistry. Bi(N 3 ) 3 ⋅THF qualifies as a good precursor for the generation of binary BiN owing to its low shock and heat sensitivity, in contrast to pure, highly sensitive Bi(N 3 ) 3 .