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The Reaction of Organozinc Compounds with an Aldehyde within a Crystalline Molecular Flask
Author(s) -
Ikemoto Koki,
Inokuma Yasuhide,
Fujita Makoto
Publication year - 2010
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201002053
Subject(s) - aldehyde , crystallinity , single crystal , chemistry , crystal structure , crystal (programming language) , organic chemistry , polymer chemistry , crystallography , catalysis , computer science , programming language
Organozinc addition reactions were carried out on an aldehyde within a porous coordination network (see picture) in a single‐crystal‐to‐single‐crystal fashion, and the product structure was unambiguously determined by X‐ray diffraction. Moreover, a one‐pot two‐step reaction in a single crystal furnished an ester from an aldehyde without the network losing crystallinity.